Ion contained in the compound | Solubility | Exceptions |
Group IA (Li+, Na+, K+, Rb+, Cs+) and NH4+ | Soluble | none |
Nitrates (NO3-) and acetates (C2H3O2-) | Soluble | none |
Chlorides (Cl-), bromides (Br-), and iodides (I-) | Soluble | Ag+, Pb2+, Hg22+ |
Sulfates (SO42-) | Soluble | Ba2+, Ca2+, Pb2+, Hg2+ |
Carbonates (CO32-) and phosphates (PO43-) | Insoluble1 | Group IA and NH4+ |
Chromate (CrO42-) and oxalates (C2O42-) | Insoluble | Group IA and NH4+ |
Sulfides (S2-) and oxides (O2-) | Insoluble | Group IA, IIA and NH4+ |
Hydroxides (OH- ) | Insoluble | Group IA, Ba2+, Sr2+, Ca2+ |
1All ionic compounds, even the least soluble ones, dissolve to some slight extent in water. Thus, the "Insoluble" classification really means ionic compounds that have very limited solubility in water. Remember that salts containing the "Insoluble" anions are always soluble with Group IA metals and ammonium ions.
Balancing Redox (Oxidation-Reduction) Reactions
After you identify the elements (or compounds) that will be oxidized or reduced,
set up two half-reactions, one for oxidation (loss of electrons) and for
reduction (gain of electrons). You do not need to determine which one is
oxidation or reduction, but you need to identify the correct compounds, or
elements, that change oxidation state.
1Balance the non-oxygen and non-hydrogen
atoms, which are usually those undergoing oxidation or reduction
2Add water to make the number of O-atoms the same on both sides
3Add H+ to make number of H-atoms the same on both sides
4Determine the charge on each side; add enough electrons to make
charge same on both sides (electrons added to least negative side, or most
positive side).
5If necessary multiply each reaction by
an interger to give same number of electrons gained and lost
Example Redox Balancing:
Reaction to Balance: Cu + HNO3
→ Cu2+ + NO2
Copper Half Reaction: Cu
→ Cu2+ + 2e-
Nitrogen Half Reaction: 1e- + H+ + HNO3
→ NO2 + H2O or x2 (1e- + H+
+ HNO3
→ NO2 + H2O)
Final Nitrogen Half Reaction: 2e- + 2H+ + 2HNO3
→ 2NO2 + 2H2O
Final Equation: Cu + 2H+ + 2HNO3
→ Cu2+ 2NO2 + 2H2O